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Abnormally Mild Synthesis of Bis(dithiolo)pyrroles from 2,5-Dimethylpyrroles.

✍ Scribed by Stanislav A. Amelichev; Rinat R. Aysin; Lidia S. Konstantinova; Natalia V. Obruchnikova; Oleg A. Rakitin; Charles W. Rees


Publisher
John Wiley and Sons
Year
2006
Weight
20 KB
Volume
37
Category
Article
ISSN
0931-7597

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Convenient synthesis of 1-alkyl-2, 5-bis
✍ In Tae Kim; Ronald L. Elsenbaumer πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 French βš– 187 KB

Aminomethylation of 1-alkylpyrrole (alkyl: hydrogen, methyl, hexyl, dodecyl )by aqueous formaldehyde and dimethylamine hydrochloride, followed by reaction with iodomethane, affords the l-alkyl-2,5-bis[ (trimethylamino) mCdiyl]pyrrole diiodide. These diiodide salt derivatives react with sodium thioph