Ab initiostudy of the complexes of first-row transition-metal ions with CH, CH2, and CH3
β Scribed by Jihai Li; Dacheng Feng; Shengyu Feng
- Publisher
- SP Science China Press
- Year
- 1999
- Tongue
- English
- Weight
- 430 KB
- Volume
- 42
- Category
- Article
- ISSN
- 1674-7291
No coin nor oath required. For personal study only.
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## Photoionization mass spectrometry was used to investigate the dynamics of ion-neutral complex-mediated dissociations of the Iz-pentane ion (1). Reinterpretation of previous data demonstrates that a fraction of ions 1 isomerizes to the 2-methylbutane ion (2) through the complex [CHaCH+CHa'CH,CH,
Rate constants for the reactions of OH radicals and Cl atoms with CH,CH,NO>, CH,CH,CH,NO,, CH3CH2CH2CHzN02, and CH,CH2CH2CH,CH2N02 have been determined at 295+3 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rate technique of pulse radiolysis co