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A Zintl phase with a layered network structure, potassium silicon arsenide (KSi3As3)

โœ Scribed by Hurng, Weir Mirn; Corbett, John D.; Wang, Sue Lein; Jacobson, Robert A.


Book ID
121705009
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
540 KB
Volume
26
Category
Article
ISSN
0020-1669

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ChemInform Abstract: Na5Sn13: A New Zint
โœ J. T. VAUGHEY; J. D. CORBETT ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 30 KB ๐Ÿ‘ 1 views

The new title compound is obtained in ยฟ 95% yield from a stoichiometric Na-Sn mixture upon heating at 800 โ€ข C and annealing of the quenched mixture for 10 weeks at 280 โ€ข C. As revealed from the single-crystal XRD data, the three-dimensional structure (orthorhombic, Cmcm, Z = 16) consists of infinite