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Na 5 Sn 13 : A New Zintl Phase with a Complex Network Structure Constructed from Tin Pentagons

โœ Scribed by Vaughey, J. T.; Corbett, John D.


Book ID
125960086
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
359 KB
Volume
36
Category
Article
ISSN
0020-1669

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ChemInform Abstract: Na5Sn13: A New Zint
โœ J. T. VAUGHEY; J. D. CORBETT ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 30 KB ๐Ÿ‘ 1 views

The new title compound is obtained in ยฟ 95% yield from a stoichiometric Na-Sn mixture upon heating at 800 โ€ข C and annealing of the quenched mixture for 10 weeks at 280 โ€ข C. As revealed from the single-crystal XRD data, the three-dimensional structure (orthorhombic, Cmcm, Z = 16) consists of infinite