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A xanthate-based free radical approach to defucogilvocarcin M

✍ Scribed by Omar Cortezano-Arellano; Alejandro Cordero-Vargas

Publisher
Elsevier Science
Year
2010
Tongue
French
Weight
527 KB
Volume
51
Category
Article
ISSN
0040-4039

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✦ Synopsis

A formal total synthesis of the aglycon of gilvocarcin M is described. The synthesis is based on the construction of the key naphthalene 7 via a free radical addition-cyclization protocol followed by aromatization of the resulting a-tetralone. This highly functionalized aromatic system is coupled to the

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