𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A novel free-radical approach to methylenomycin B[1]

✍ Scribed by Piotr Bałczewski

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
153 KB
Volume
8
Category
Article
ISSN
1042-7163

No coin nor oath required. For personal study only.

✦ Synopsis

A new free-radical strategy for the synthesis of ␣-functionalized diethyl b-ketophosphonates utilizing diethyl b-ketophosphonyl ␣-radical is exemplified by the formal synthesis of methylenomycin B-a cyclopentanoid antibiotic.

📜 SIMILAR VOLUMES

A TEMPO-mediated “living” free-radical a
A TEMPO-mediated “living” free-radical approach to ABA triblock dendritic linear hybrid copolymers
✍ Todd Emrick; Wayne Hayes; Jean M. J. Fréchet 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 175 KB

Dumbbell-shaped ABA triblock copolymers composed of benzyl ether dendrons and polystyrene as the A and B blocks, respectively, were prepared using 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO) -mediated "living" free-radical polymerization. A new bis-dendritic unimolecular initiator, compound 3, was

Free Radical Chemistry. 13 [1] Addition
Free Radical Chemistry. 13 [1] Addition of Alkyl-Cyclohexanol Derivatives to Hexafluoropropene
✍ Richard D. Chambers; Christopher Farren; Graham Sandford; Dmitri S. Yufit; Judit 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 103 KB 👁 1 views

Free radicals derived from some alkyl substituted cyclohexanol derivatives react with hexafluoropropene to give a variety of polyfluoroalkylated adducts. Stereochemistry of the processes is discussed and remote functionalisation of the methyl group in Chemie freier Radikale. 13. Addition von Alkylcy