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A Tandem Approach to Graft and Dendritic Graft Copolymers Based on “Living” Free Radical Polymerizations

✍ Scribed by Robert B. Grubbs; Dr. Craig J. Hawker; Julian Dao; Prof. Dr. Jean M. J. Fréchet


Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
417 KB
Volume
36
Category
Article
ISSN
0044-8249

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A TEMPO-mediated “living” free-radical a
✍ Todd Emrick; Wayne Hayes; Jean M. J. Fréchet 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 175 KB 👁 1 views

Dumbbell-shaped ABA triblock copolymers composed of benzyl ether dendrons and polystyrene as the A and B blocks, respectively, were prepared using 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO) -mediated "living" free-radical polymerization. A new bis-dendritic unimolecular initiator, compound 3, was