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A Versatile Co(bisalen) Unit for Homogeneous and Heterogeneous Cooperative Catalysis in the Hydrolytic Kinetic Resolution of Epoxides

✍ Scribed by Krishnan Venkatasubbaiah; Christopher S. Gill; Tait Takatani; C. David Sherrill; Christopher W. Jones


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
242 KB
Volume
15
Category
Article
ISSN
0947-6539

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✍ Sander J. Wezenberg; Arjan W. Kleij 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 274 KB 👁 1 views

## Abstract A chiral, bimetallic cobalt(III)salen‐calix[4]arene hybrid structure was prepared and tested in the hydrolytic kinetic resolution (HKR) of racemic epoxides. Kinetic studies have revealed that the two catalytic units on the upper rim of the calixarene scaffold are able to activate the re