Transient alkyl radicals and triplet-state molecules are generated simultaneously in solution by laser flash irradiation, and chemically induced electron polarization (CIDEP) of the radicals is studied by time-resolved ESR spectroscopy. The presence of triplet-state molecules is found to induce emis
A variational solution of the stochastic liouville model of chemically induced electron polarization in radical pairs
β Scribed by Frank J. Adrian
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 412 KB
- Volume
- 80
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
A variational solution is proposed for the integral equation form of the stochastic Liouville equations describing the radical pair mechanism of chemically induced electron polarization.
π SIMILAR VOLUMES
In flash-photolysis experiments the phase of RPM polarization in the radicals commonly changes in time after the flash, the patterns observed at longer times being apparently inconsistent with observations on the same radical systems made using alternative experimental techniques. It is shown here t
It is found that intersgstem crossings between the singlet and the MS = fl components of the triplet state of radical p&in liquids can produce nuclear and electron spin polarizations when two radicals diffuse apart follOWing arl initial encounter and subsequently undergo a second nonreactive encount
## Abstract __Protonβtransfer reactions of the radical anion and cation of the 7βAzaindole (7AI) dimer were investigated by means of density functional theory (DFT). The calculated results for the dimer anion and cation were very similar. Three equilibrium structures, which correspond to the nonβpr