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A two-step chirality transfer from (−)-endo- to (−)-exo-tricyclo[5.2.1.026]deca-4,8-dien-3-one

✍ Scribed by Paul P.M.A. Dols; Antonius J.H. Klunder; Binne Zwanenburg

Book ID
108382178
Publisher
Elsevier Science
Year
1993
Tongue
French
Weight
336 KB
Volume
34
Category
Article
ISSN
0040-4039

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ChemInform Abstract: Asymmetric Desymmet
ChemInform Abstract: Asymmetric Desymmetrization of a Pseudo-meso endo-Tricyclo(5.2.1.02,6) deca-4,8-dien-3-one by Chiral Amines.
✍ F. J. A. D. BAKKEREN; N. G. RAMESH; D. DE GROOT; A. J. H. KLUNDER; B. ZWANENBURG 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 1 views

## Asymmetric Desymmetrization of a Pseudo-meso endo-Tricyclo(5.2.1.02,6) deca-4,8-dien-3-one by Chiral Amines. -The title compound (I) undergoes a dynamic kinetic resolution to enaminones (III) applying prolinol or its methyl ether as chiral mediators. Reductive elimination of the chiral auxilia