served re6ections with I'2 (I)]. The structure of I comprises a network of ZnO 4 , PO 4 , and PO 3 (OH) tetrahedra forming one-dimensional tubes. The tubes, in turn, are linked via oxygen atoms forming macroanionic inorganic layers with eight-membered apertures. The one-dimensional tube-like archite
A Two-Dimensional Cationic Lattice Built from [Zn6(HPO4)2(PO4)2] 2+ Clusters.
β Scribed by Jian Fan; Brian E. Hanson
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 14 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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A 4-membered ring zinc phosphate monomer, I, [C 6 N 2 H 18 ] 2Ψ [Zn(HPO 4 )(H 2 PO 4 ) 2 ] 2Ψ , has been isolated by the reaction of the Zn 2Ψ with the amine, N,N,N,N-tetramethylethylenediamine (TMED) and H 3 PO 4 at room temperature over an extended period of time. It could also be prepared by the