✦ LIBER ✦

A Three-Dimensional Iron(III) Phosphate, [C2N2H10]2[Fe5F4(PO4)(HPO4)6]

✍ Scribed by Amitava Choudhury; Srinivasan Natarajan

Publisher: Elsevier Science
Year: 2000
Tongue: English
Weight: 282 KB
Volume: 154
Category: Article
ISSN: 0022-4596
DOI: 10.1006/jssc.2000.8871

No coin nor oath required. For personal study only.

✦ Synopsis

A new iron phosphate, [C 2 N 2 H 10 ] 2 [Fe 5 F 4 (PO 4 )(HPO 4 ) 6 ], containing F ؊ ions as part of the framework, has been synthesized hydrothermally using iron acetylacetonate as the source for iron and ethylenediamine (en) as the amine. A network of [Fe(O/F) 6 ] octahedra and PO 4 tetrahedra, linked through their vertices, forms the three-dimensional architecture with one-dimensional channels bound by 8-T atom (T ‫؍‬ Fe, P), wherein the disordered en molecules are located. The connectivity between the Fe centers via Fe+O/F+Fe linkage giving rise to a pentamer unit is worthy of note.

📜 SIMILAR VOLUMES

A New Three-Dimensional Cobalt Phosphate

A New Three-Dimensional Cobalt Phosphate: Co5(OH2)4(HPO4)2 (PO4)2.

✍ Zhangang Han; Aixiang Tian; Jun Peng; Xueliang Zhai 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 10 KB

ChemInform Abstract: Two New Mixed-Valen

ChemInform Abstract: Two New Mixed-Valence Iron Phosphates Templated by Piperazine: (C4H12N2) [Fe4(OH)2(HPO4)5] and (C4H11N2)0.5 [Fe3(HPO4)2(PO4) (H2O)].

✍ V. ZIMA; K.-H. LII; NGUYEN NINH NGUYEN NINH; A. DUCOURET 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 1 views

ChemInform Abstract: Hydrothermal Synthe

ChemInform Abstract: Hydrothermal Synthesis and Structural Characterization of Three Organically Templated Titanium Phosphates: Ti2(HPO4)2 (PO4)2×C2N2H10, Ti3(H2PO4)(HPO4)3.5 (PO4)2×C2N2H10, and Ti7(HPO4)6 (PO4)6×C3N2H12.

✍ Yunling Liu; Zhan Shi; Yunlong Fu; Wei Chen; Baozong Li; Jia Hua; Wuyang Liu; Fe 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 38 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

Hydrothermal Synthesis and Structural Ch

Hydrothermal Synthesis and Structural Characterization of Two New Three-Dimensional Oxyfluorinated Titanium PhosphatesTi4(HPO4)2(PO4)4F2·C4N2H12·H2O and Ti4(HPO4)2(PO4)4F2·C2N2H10·H2O

✍ Yunlong Fu; Yunling Liu; Zhan Shi; Yongcun Zou; Wenqin Pang 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 416 KB

Two new organo-templated three-dimensional 6uorinated titanium phosphates Ti 4 (HPO 4 ) 2 (PO 4 ) 4 F 2 ' C 4 N 2 H 12 ' H 2 O 1 and Ti 4 (HPO 4 ) 2 (PO 4 ) 4 F 2 ' C 2 N 2 H 10 ' H 2 O 2 have been prepared hydrothermally in the presence of piperazine (C 4 N 2 H 10 ) and ethylenediamine (C 2 N 2 H 8

Synthesis of Open-Framework Iron Phospha

Synthesis of Open-Framework Iron Phosphates, [C6N2H14][FeIII2F2(HPO4)2(H2PO4)2]·2H2O and [C6N2H14]2[FeIII3(OH)F3(PO4)(HPO4)2]2·H2O, with One- and Three-Dimensional Structures

✍ S. Mahesh; Mark A. Green; Srinivasan Natarajan 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 485 KB

The hydrothermal syntheses and structures of two new open-framework iron phosphates, I, [C 6 N 2 H 14 ][Fe III 2 F 2 (HPO 4 ) 2 (H 2 PO 4 ) 2 ].2H 2 O, II, and [C 6 N 2 H 14 ] 2 [Fe III 3 (OH)F 3 (PO 4 ) (HPO 4 ) 2 ] 2 . H 2 O, are presented. The structures of both I and II consist of FeO 4 F 2 octa

[N2C6H14]2 [(UO2)6(H2O)2F2 (PO4)2(HPO4)4

[N2C6H14]2 [(UO2)6(H2O)2F2 (PO4)2(HPO4)4] ×4H2O: A New Microporous Uranium Phosphate Fluoride.

✍ Michael B. Doran; Clair L. Stuart; Alexander J. Norquist; Dermot O'Hare 📂 Article 📅 2004 🏛 John Wiley and Sons ⚖ 59 KB 👁 1 views