A Layered Zinc Phosphate, [C6N4H22][Zn6(PO4)4(HPO4)2], Formed by One-Dimensional Tubes
β Scribed by Amitava Choudhury; Srinivasan Natarajan; C.N.R. Rao
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- English
- Weight
- 252 KB
- Volume
- 157
- Category
- Article
- ISSN
- 0022-4596
No coin nor oath required. For personal study only.
β¦ Synopsis
served re6ections with I'2 (I)]. The structure of I comprises a network of ZnO 4 , PO 4 , and PO 3 (OH) tetrahedra forming one-dimensional tubes. The tubes, in turn, are linked via oxygen atoms forming macroanionic inorganic layers with eight-membered apertures. The one-dimensional tube-like architecture in I is a novel feature worthy of note.
π SIMILAR VOLUMES
A 4-membered ring zinc phosphate monomer, I, [C 6 N 2 H 18 ] 2Ψ [Zn(HPO 4 )(H 2 PO 4 ) 2 ] 2Ψ , has been isolated by the reaction of the Zn 2Ψ with the amine, N,N,N,N-tetramethylethylenediamine (TMED) and H 3 PO 4 at room temperature over an extended period of time. It could also be prepared by the
A new iron phosphate, [C 2 N 2 H 10 ] 2 [Fe 5 F 4 (PO 4 )(HPO 4 ) 6 ], containing F Ψ ions as part of the framework, has been synthesized hydrothermally using iron acetylacetonate as the source for iron and ethylenediamine (en) as the amine. A network of [Fe(O/F) 6 ] octahedra and PO 4 tetrahedra, l
A new zinc phosphate, (C 10 N 4 H 28 )[Zn 6 (HPO 4 ) 2 (PO 4 ) 4 ] ' 2H 2 O, with a layered architecture has been synthesized, for the 5rst time, in the presence of 1,4-bis(3-aminopropyl)piperazine as the structure-directing agent. The structure comprises a network of ZnO 4 and phosphate tetrahedra