✦ LIBER ✦

A theory explaining chemically induced nuclear spin polarization in radical transfer and disproportionation reactions

✍ Scribed by F. Gerhart; G. Ostermann

Book ID: 104240115
Publisher: Elsevier Science
Year: 1969
Tongue: French
Weight: 250 KB
Volume: 10
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)88789-x

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✦ Synopsis

Nuclear spin polarization in free radical transfer reactions may be explained, in some cases, by dynamic nuclear polarization (CIDNP) occurring in the free radical (1). This mechanism, however, cannot account for the "multiplet-effects" frequently observed in radical transfer (2,3), disproportionation (21, and recombination reactions (4). For the latter, the multiplet-effect (ME) has been

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