AhstraceThe anodic behaviour of pure, recrystallized iron in acid sulphate and perchlorate solutions free of oxygen and surface active substances was investigated in the potential range between the active and passive stzite. The measurements were carried out using an iron rotating disk electrode by
A theoretical treatment of the kinetics of iron dissolution and passivation
β Scribed by A.A. El Miligy; D. Geana; W.J. Lorenz
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 690 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0013-4686
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β¦ Synopsis
~The anodic behuviour of highly pure iron in weak acid aqueous solutions which are free of oxygen and surface active compounds takes place in dllTerent ranges: active dissolution, Lransitlon range. prepassive range and passive state. This is indicated by the experimentally ohserved current-density potential curves which show a maximum I and a minimum in the transition range, a further increase in the prepasslve range and il maximum 11 before reaching the passive state. Different mechanisms including
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By the Poisson equation solution using Fermi-Dirac statistics for a degenerate electron gas a formula for calculation of doping density N z lOi cnm3 and flat band potential E, at 300 K is derived according to the Mott-Schottky equation. The relationships for estimation of the depletion band bending
## Abstract The kinetics of dissolution have been expressed using a generalized dissolution rate equation which combines concentration driving force and area terms and thus enables large amounts of undersaturation to be used in experiments.