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A theoretical treatment of nucleophilic reactivity in additions to carbonyl compounds. Role of the vertical ionization energy

โœ Scribed by Buncel, Erwin.; Shaik, Sason S.; Um, Ik Hwan.; Wolfe, Saul.


Book ID
127373828
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
648 KB
Volume
110
Category
Article
ISSN
0002-7863

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As we haVe previously pointed out], the position of the Transition State along the reaction coordinate is a matter of controversy among workers in the field of nucleophilic addition reactions to carbonyl compounds. Some authors claim that the transition state is always "Reactant-like" whatever may b