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A Test of Dielectric Friction Models. Rotational Diffusion of Fluorenes in Dimethyl sulfoxide

✍ Scribed by Hartman, R. S.; Waldeck, D. H.


Book ID
120308746
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
892 KB
Volume
98
Category
Article
ISSN
0022-3654

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A microscopic theory of the effects of dipolar solvents dynamics on the dielectric friction of a rotating dipolar solute is presented. We predict that translational diffusion of solvent molecules can significantly reduce the value of the zero-frequency dielectric friction. We find that the orientati