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Rotational Diffusion of Coumarins: A Dielectric Friction Study

โœ Scribed by J. R. Mannekutla; Sanjeev R. Inamdar; B. G. Mulimani; M. I. Savadatti


Book ID
106412823
Publisher
Springer
Year
2010
Tongue
English
Weight
329 KB
Volume
20
Category
Article
ISSN
1053-0509

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Effects of translational diffusion on di
โœ G.V. Vijayadamodar; A. Chandra; B. Bagchi ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 522 KB

A microscopic theory of the effects of dipolar solvents dynamics on the dielectric friction of a rotating dipolar solute is presented. We predict that translational diffusion of solvent molecules can significantly reduce the value of the zero-frequency dielectric friction. We find that the orientati