𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A synthesis of (S,S)-(+)-grahamimycin A1

✍ Scribed by Dario Ghiringhelli


Book ID
104216906
Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
218 KB
Volume
24
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Total synthesis of (-)-grahamimycin A1
✍ Hillis, Larry R.; Ronald, Robert C. πŸ“‚ Article πŸ“… 1985 πŸ› American Chemical Society 🌐 English βš– 618 KB
Grahamimycin A1: a novel dilactone antib
✍ Robert C. Ronald; S. Gurusiddaiah πŸ“‚ Article πŸ“… 1980 πŸ› Elsevier Science 🌐 French βš– 256 KB

By means of spectral and chemical studies the structure of Grahamimycin Al 1, a novel macrocyclic dilactone antibiotic from Cytospora, is established. As part of a program investigating fungi of the genus Cytospora as a source of novel biologically active substances, we observed that aerobically gro

First Total Synthesis of Grahamimycin A
✍ Kobayashi, Yuichi; Matsuumi, Michitaka πŸ“‚ Article πŸ“… 2000 πŸ› American Chemical Society 🌐 English βš– 72 KB
Totalsynthese des macrodiolids (r,r)-(βˆ’)
✍ Hans-JΓΌrgen Bestmann; Rainer Schobert πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 French βš– 215 KB

The title compound is synthesized by use of the easily accessible aldehyde 3 for establishing both chiral centres and of ketenylidentriphenylphosphorane for cyclization. In contrast to literature our product is not an antibiotic. Ronald und Gurusiddaiah 1 berichteten 1980 iiber die Isolierung von (-