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A Study of β-Amino-α,β-unsaturated Ketones 1

✍ Scribed by WEINSTEIN, JULIUS; WYMAN, GEORGE M.


Book ID
126131304
Publisher
American Chemical Society
Year
1958
Tongue
English
Weight
533 KB
Volume
23
Category
Article
ISSN
0022-3263

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Aziridination of α,β-unsaturated ketones
✍ Stefania Fioravanti; Lucio Pellacani; Stefania Tabanella; Paolo A. Tardella 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 411 KB

Akstra~. ~l~-Unsaturated ketones are aziridinated by [(arenesulphonyl)oxy]carbamates and CaO (or Cs2CO3) or by N3CO2Et photolysis. A remote chiral center induced up m 74% ~e. Bis-unsaturated subeuates showed scarce regioselectivity under all conditions.