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Aziridination of α,β-unsaturated ketones

✍ Scribed by Stefania Fioravanti; Lucio Pellacani; Stefania Tabanella; Paolo A. Tardella

Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
411 KB
Volume
54
Category
Article
ISSN
0040-4020

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✦ Synopsis

Akstra~. ~l~-Unsaturated ketones are aziridinated by [(arenesulphonyl)oxy]carbamates and CaO (or Cs2CO3) or by N3CO2Et photolysis. A remote chiral center induced up m 74% ~e. Bis-unsaturated subeuates showed scarce regioselectivity under all conditions.

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