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The Conversion of α,β-Unsaturated Ketones Into β-(Phenyl-Thio)-α,β-Unsaturated Ketones

✍ Scribed by Groot, Aede de; Peperzak, Rob M.; Vader, Jan


Book ID
120299503
Publisher
Taylor and Francis Group
Year
1987
Tongue
English
Weight
302 KB
Volume
17
Category
Article
ISSN
0039-7911

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## Abstract For Abstract see ChemInform Abstract in Full Text.

Deconjugation of α,β-unsaturated ketones
✍ Howard J. Ringold; Sudarshan K. Malhotra 📂 Article 📅 1962 🏛 Elsevier Science 🌐 French ⚖ 192 KB

BIRCH' demonstrated in 1950 that a steroidal a,p-unsaturated ketone (I) may be deconjugated to its p,y-unsaturated ketone isomer (III) by irreversible protonation of the conjugate anion (II), however, the requisite anion has been prepared only by indirect means (e.g. through the enol acetate, 132 fr