Flash photolysis kinetic absorption spectroscopy was used to investigate the gas phase disproportionation reaction of CH302 radicals over the temperature range 228-380 K at pressures between 50 and 400 Torr of nitrogen diluent. The measured secondorder rate constants, defined by the expression -d[ C
β¦ LIBER β¦
A study of the temperature dependence of the rate constant for the reaction of O2with surface alkoxy radicals
β Scribed by Stepanov, A. V.; Shestakov, D. V.
- Book ID
- 118152432
- Publisher
- Pleiades Publishing
- Year
- 2012
- Tongue
- English
- Weight
- 145 KB
- Volume
- 6
- Category
- Article
- ISSN
- 1990-7931
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## Abstract Absolute rate constants for the reaction of OH with H~2~S have been measured over the temperature range of 239β425 K using the flash photolysisβresonance fluorescence technique. The results showed that the rate constants deviate slightly from Arrhenius behavior but can still be represen