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A study of the negative ion states of selected cyclodienes by electron transmission spectroscopy

✍ Scribed by K.D. Jordan; J.A. Michejda; P.D. Burrow

Publisher: Elsevier Science
Year: 1976
Tongue: English
Weight: 485 KB
Volume: 42
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(76)80352-1

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✦ Synopsis

Electron transmission spectroscopy is employed to locate sharp variations in the total cross sections for electrons scattered from several cyclic compounds containing two carbon-carbon double bonds. For each molecule, structure is observed which we associate with the temporary occupation of the two low-lyin g, normally unfilled, P* orbitah by impacting eIectrons. Electron affinities are reported for lJ-cyclooctadiene, 1,4-and 1,3_cyclohexadiene, norbornadiene and also cyclohexene, propene, and cis-butcne.

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