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A stereoselective total synthesis of the Prelog-Djerassi lactone

โœ Scribed by Bartlett, Paul A.; Adams, Jerry L.

Book ID
127071903
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
734 KB
Volume
102
Category
Article
ISSN
0002-7863

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A new approach to the synthesis of Prelog-Djerassi Lactonic acid (1) is reported. A key step in this synthesis involves an lreland-Claisen rearrangement/silicon-mediated fragmentation sequence to provide the carbon framework in (1).