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A stereoselective synthesis of the spirosesquiterpene (−)-acorenone

✍ Scribed by G.L. Lange; Will J. Orrom; David J. Wallace

Book ID
104235839
Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
115 KB
Volume
18
Category
Article
ISSN
0040-4039

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✍ Wolfgang Oppolzer; Kumar K. Mahalanabis; Kurt Bättig 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 German ⚖ 929 KB

## Abstract The racemic spirosesquiterpenes β‐acorenol (**1**), β‐acoradiene (**2**), acorenone‐B (**3**) and acorenone (**4**) (__Scheme 2__) have been synthesized in a simple, flexible and highly stereoselective manner from the ester **5**. The key step (__Schemes 3__ and __4__), an intramolecula