Arene-metal complexes in organic synthesis: synthesis of acorenone and acorenone B
✍ Scribed by Semmelhack, M. F.; Yamashita, A.
- Book ID
- 127200531
- Publisher
- American Chemical Society
- Year
- 1980
- Tongue
- English
- Weight
- 388 KB
- Volume
- 102
- Category
- Article
- ISSN
- 0002-7863
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📜 SIMILAR VOLUMES
## Abstract The racemic spirosesquiterpenes β‐acorenol (**1**), β‐acoradiene (**2**), acorenone‐B (**3**) and acorenone (**4**) (__Scheme 2__) have been synthesized in a simple, flexible and highly stereoselective manner from the ester **5**. The key step (__Schemes 3__ and __4__), an intramolecula
Metal-arene pi-complexes show a rich and varied chemistry. The metal adds a third dimension to the planar aromatic compounds and coordination of a metal to an arene thus not only altering the reactivity of ring-carbons and substituents but also makes possible reactions that lead to chiral non-racemi