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A stereochemically general synthesis of methyl 2,4,6-trideoxy-4-methylthio-α-D-ribo-pyranoside, the thio sugar of esperamicin A1

✍ Scribed by William R. Roush; Darin Gustin

Publisher: Elsevier Science
Year: 1994
Tongue: French
Weight: 417 KB
Volume: 35
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)73285-0

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✦ Synopsis

Actor.

A sleazy general synthesis of methyl 2,4,~~xyJI_a-~~~p~oside (lb), the thio sugar isolated from esperamicin, is described. 'I%e synthesis involves the neighbori& group assisted

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