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A Stable Rearrangement Product of Humulene-4,5-epoxide

โœ Scribed by Carman, Raymond M.


Book ID
126864871
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
58 KB
Volume
68
Category
Article
ISSN
0163-3864

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๐Ÿ“œ SIMILAR VOLUMES


Rearrangement of humulene-8,9-epoxide
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Rearrangement of humulene-6,9-epoxide with tin(IV) chloride leads to the formation of a bicyclic alcohol,the structure of which is related to a rearrangement product of humulene itself. The three mono-epoxides of humulene ( 1) -( 3) are naturally-occurring'

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Rearrangement of humulene-4,5-epoxide with boron trifluoride etherate leads to the formation of two tricyclic alcohols the structures of which are closely related to that of africanol; the z-ray structure of the E-bromobenzoate of one of the alcohols is reported.

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โœ Steven P. Tanis; Yousef M. Abdallah; Paul G. Williard ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 303 KB

g oxidation selectivity of a number of 4 r-dimethyl-1,2,3,4,6,8a-hexahydronapht alenes 4 were examined. Exposure of the isolated a-epoxides 7 provided excellent yields (79-92x) of rearranged fused indene-oxetanes 8. Treatment of dF\_epoxides 5 with BF3\* OEtz also yields oxetanes 6 and related alcoh