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Rearrangement of humulene-8,9-epoxide

✍ Scribed by Ian Bryson; James S Roberts; Abdul Sattar

Publisher: Elsevier Science
Year: 1980
Tongue: French
Weight: 177 KB
Volume: 21
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)71413-4

No coin nor oath required. For personal study only.

✦ Synopsis

Rearrangement of humulene-6,9-epoxide with tin(IV) chloride leads to the formation of a bicyclic alcohol,the structure of which is related to a rearrangement product of humulene itself.

The three mono-epoxides of humulene ( 1) -( 3) are naturally-occurring'

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