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A Spirocyclic Chiral Borate for Catalytic Enantioselective Nozaki-Hiyama Allylation of Ketones

✍ Scribed by Xin-Ren Huang; Chinpiao Chen; Gene-Hsian Lee; Shie-Ming Peng

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
210 KB
Volume
351
Category
Article
ISSN
1615-4150

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Application of Tridentate Bis(oxazoline) Ligands in Catalytic Asymmetric Nozaki–Hiyama Allylation and Crotylation: An Example of High Enantioselection with a Non-Symmetric Bis(oxazoline) Ligand
✍ Helen A. McManus; Pier Giorgio Cozzi; Patrick J. Guiry 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 115 KB 👁 1 views

## Abstract A series of both symmetric and non‐symmetric bis(oxazoline) ligands was applied in the Nozaki–Hiyama allylation and crotylation of benzaldehyde. It was found that both the magnitude and sense of the asymmetric induction depended strongly on the nature and combination of the oxazoline su