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A Highly Enantioselective Catalyst for the Asymmetric Nozaki–Hiyama–Kishi Reaction of Allylic and Vinylic Halides

✍ Scribed by Albrecht Berkessel; Dirk Menche; Christoph A. Sklorz; Michael Schröder; Ian Paterson


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
111 KB
Volume
42
Category
Article
ISSN
0044-8249

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## Abstract Here, we describe the successful application of novel glucofuranose‐derived 1,3‐diphosphites in the rhodium‐catalysed asymmetric hydroformylation of vinyl acetate, 2,5‐dihydrofuran and 2,3‐dihydrofuran. In the hydroformylation of vinyl acetate, total regioselectivity and high __ee__ (up