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A Highly Enantioselective Catalyst for the Asymmetric Nozaki—Hiyama—Kishi Reaction of Allylic and Vinylic Halides.

✍ Scribed by Albrecht Berkessel; Dirk Menche; Christoph A. Sklorz; Michael Schroeder; Ian Paterson

Publisher
John Wiley and Sons
Year
2003
Weight
172 KB
Volume
34
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

📜 SIMILAR VOLUMES

Highly Efficient Rhodium Catalysts for t
Highly Efficient Rhodium Catalysts for the Asymmetric Hydroformylation of Vinyl and Allyl Ethers using C1-Symmetrical Diphosphite Ligands
✍ Aitor Gual; Cyril Godard; Sergio Castillón; Carmen Claver 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 479 KB 👁 1 views

## Abstract Here, we describe the successful application of novel glucofuranose‐derived 1,3‐diphosphites in the rhodium‐catalysed asymmetric hydroformylation of vinyl acetate, 2,5‐dihydrofuran and 2,3‐dihydrofuran. In the hydroformylation of vinyl acetate, total regioselectivity and high __ee__ (up