The first asymmetric synthesis of chiral
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Dusan Hesek; Yoshihisa Inoue; Hitoshi Ishida; Simon R.L Everitt; Michael G.B Dre
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Article
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2000
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Elsevier Science
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French
β 115 KB
The first 'one-pot' asymmetric synthesis of ruthenium tris(bipyridine) derivatives starting from corresponding racemic ruthenium bis(bipyridine) complexes is described. This is achieved through the stereocontrolled formation of reactive intermediates derived from (R)-(+)-or (S)-(-)-methyl p-tolyl su