Bis(2,2′bipyridine) ruthenium(II) complexes
✍ Scribed by John A. Broomhead; Oliver Ileperuma
- Book ID
- 118910565
- Publisher
- Elsevier Science
- Year
- 1981
- Weight
- 114 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0022-1902
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## Abstract The existence of two independent chromophores in [Ru(bipy)~2~(H~2~V)]^+^, where H~2~V^−^ = violurate anion and bipy = 2,2′bipyridine, was demonstrated by comparing its resonance Raman spectra with those displayed by the [Ru(H~2~V)~3~]^−^ analogue. In the former, the electronic band at 4
We have synthesized a new type of tris-2,2'-bipyridine ligand of 7 and 8 do not interact appreciably, as is evident from their with 4,4'-and 6,6'-disubstituted 2,2'-bipyridine (bpy) units. electrochemical and photophysical data. The lifetime of the The terminal 4,4'-disubstituted 2,2'-bipyridine moi