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The first asymmetric synthesis of chiral ruthenium tris(bipyridine) from racemic ruthenium bis(bipyridine) complexes

✍ Scribed by Dusan Hesek; Yoshihisa Inoue; Hitoshi Ishida; Simon R.L Everitt; Michael G.B Drew

Book ID: 104210098
Publisher: Elsevier Science
Year: 2000
Tongue: French
Weight: 115 KB
Volume: 41
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)00230-6

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✦ Synopsis

The first 'one-pot' asymmetric synthesis of ruthenium tris(bipyridine) derivatives starting from corresponding racemic ruthenium bis(bipyridine) complexes is described. This is achieved through the stereocontrolled formation of reactive intermediates derived from (R)-(+)-or (S)-(-)-methyl p-tolyl sulfoxide, which can be easily converted to the products with a retention of configuration at the metal center.

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