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A Soluble-Polymer System for the Asymmetric Transfer Hydrogenation of Ketones.

✍ Scribed by Stephanie Bastin; Richard J. Eaves; Christopher W. Edwards; Osamu Ichihara; Mark Whittaker; Martin Wills


Publisher
John Wiley and Sons
Year
2004
Weight
22 KB
Volume
35
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES


Osmium Pyme Complexes for Fast Hydrogena
✍ Walter Baratta; Maurizio Ballico; Alessandro Delβ€…Zotto; Katia Siega; Santo Magno πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 259 KB πŸ‘ 1 views

## Abstract The osmium compound __trans__,__cis__‐[OsCl~2~(PPh~3~)~2~(Pyme)] (1) (Pyme=1‐(pyridin‐2‐yl)methanamine), obtained from [OsCl~2~(PPh~3~)~3~] and Pyme, thermally isomerizes to __cis__,__cis__‐[OsCl~2~(PPh~3~)~2~(Pyme)] (2) in mesitylene at 150 °C. Reaction of [OsCl~2~(PPh~3~)~3~] with Ph~