A new strategy for the construction of spiro [4,5]decanes is described and involves a bridgehead substitution of a methoxyl group in 6 by a methyl group, followed by an oxidative cleavage resulting in a stereogenic spirocentre which culminated in the formal synthesis of acorone.
✦ LIBER ✦
A simple strategy for spirocyclopentannulation of cyclic ketones. Formal total synthesis of (±)-acorone
✍ Scribed by Adusumili Srikrishna; P Praveen Kumar; Ranganathan Viswajanani
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- French
- Weight
- 224 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0040-4039
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