✦ LIBER ✦

A simple procedure for nucleophilic perfluoroalkylation of organic and inorganic substrates

✍ Scribed by Viacheslav A Petrov

Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 77 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)00447-6

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✦ Synopsis

The mixture R f I and tetrakis(dimethylamino)ethylene is used for the nucleophilic perfluoroalkylation. The reaction of chlorotrimethylsilane and R f I/tetrakis(dimethylamino)ethylene in diglyme results in the formation of R f Si(CH 3 ) 3 isolated in 55-81% yield. The interaction of this system with organic electrophiles such as benzoyl and benzensulphonyl chlorides, aliphatic and aromatic aldehydes and activated ketones leads to the formation of the corresponding condensation products in 24-62% yield.

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