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Nucleophiles useful for the transfer of fluorinated moieties to organic and inorganic substrates

โœ Scribed by Nimesh R. Patel; Jean'ne M. Shreeve; Robert L. Kirchmeier


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
37 KB
Volume
54
Category
Article
ISSN
0022-1139

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โœฆ Synopsis


The reactions of R$Si(CH,), (R, -CF,, C,F,, CsF,) with a variety of fluorinated organic and inorganic substrates containing a sulfur-or


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A simple procedure for nucleophilic perf
โœ Viacheslav A Petrov ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 77 KB

The mixture R f I and tetrakis(dimethylamino)ethylene is used for the nucleophilic perfluoroalkylation. The reaction of chlorotrimethylsilane and R f I/tetrakis(dimethylamino)ethylene in diglyme results in the formation of R f Si(CH 3 ) 3 isolated in 55-81% yield. The interaction of this system with