A simple procedure for nucleophilic perf
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Viacheslav A Petrov
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Article
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2001
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Elsevier Science
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French
โ 77 KB
The mixture R f I and tetrakis(dimethylamino)ethylene is used for the nucleophilic perfluoroalkylation. The reaction of chlorotrimethylsilane and R f I/tetrakis(dimethylamino)ethylene in diglyme results in the formation of R f Si(CH 3 ) 3 isolated in 55-81% yield. The interaction of this system with