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Simple Procedures for Quantification and Reuse of Common Organic Solvent Mixtures

โœ Scribed by Patrick H. Dussault; Kevin R. Woller


Publisher
Springer
Year
1996
Weight
80 KB
Volume
1
Category
Article
ISSN
1430-4171

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A simple procedure for nucleophilic perf
โœ Viacheslav A Petrov ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 77 KB

The mixture R f I and tetrakis(dimethylamino)ethylene is used for the nucleophilic perfluoroalkylation. The reaction of chlorotrimethylsilane and R f I/tetrakis(dimethylamino)ethylene in diglyme results in the formation of R f Si(CH 3 ) 3 isolated in 55-81% yield. The interaction of this system with