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A simple convenient synthesis of alkyne-Co2(CO)6 complexes and their utilization in the Pauson-Khand cyclopentenone synthesis

✍ Scribed by A. Devasagayaraj; M. Periasamy


Book ID
104227066
Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
164 KB
Volume
30
Category
Article
ISSN
0040-4039

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✦ Synopsis


Reducrion of anhydrous

CT&r2 in THF wirh zinc under carbon monoxide armosphere at room temperature followed


📜 SIMILAR VOLUMES


ChemInform Abstract: Rearrangement of 1-
✍ N. IWASAWA; T. MATSUO; M. IWAMOTO; T. IKENO 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 44 KB 👁 1 views

Rearrangement of 1-(1-Alkynyl)cyclopropanols to 2-Cyclopentenones via Their Hexacarbonyldicobalt Complexes. A New Use of Alkyne-Co 2 (CO) 6 Complexes in Organic Synthesis. -Various cyclopropanols of type (I), (III)/(VI), and (VII)/(XI) undergo in the presence of stoichiometric amounts Co 2 (CO) 8 a