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ChemInform Abstract: Alkyne—Co2(CO)6 Complexes in the Synthesis of Fused Tricyclic β-Lactam and Azetidine Systems.

✍ Scribed by B. ALCAIDE; C. POLANCO; M. A. SIERRA

Publisher
John Wiley and Sons
Year
2010
Weight
43 KB
Volume
30
Category
Article
ISSN
0931-7597

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Rearrangement of 1-(1-Alkynyl)cyclopropanols to 2-Cyclopentenones via Their Hexacarbonyldicobalt Complexes. A New Use of Alkyne-Co 2 (CO) 6 Complexes in Organic Synthesis. -Various cyclopropanols of type (I), (III)/(VI), and (VII)/(XI) undergo in the presence of stoichiometric amounts Co 2 (CO) 8 a