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A Significant Improvement of the Efficacy of Radical Oxidant Probes by the Kinetic Isotope Effect

✍ Scribed by Kousik Kundu; Sarah F. Knight; Seungjun Lee; W. Robert Taylor; Niren Murthy

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
705 KB
Volume
49
Category
Article
ISSN
0044-8249

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## Abstract The carbon kinetic isotope effect in the reaction of CH~4~ with OH has an experimentally measured value of 1.003. The measurement was performed using a static system in which the source of OH was the gas‐phase photolysis of H~2~O~2~ with ultraviolet light produced by a high‐pressure mer