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A Short Synthesis of (±)-Matrine

✍ Scribed by Laurent Boiteau; Jean Boivin; Annie Liard; Béatrice Quiclet-Sire; Samir Z. Zard

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 104 KB
Volume: 37
Category: Article
ISSN: 0044-8249
DOI: 10.1002/(sici)1521-3773(19980504)37:8<1128::aid-anie1128>3.0.co;2-p

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✦ Synopsis

Three different radical reactions were used in a short total synthesis of (±)-matrine (1). Two of the four six-membered rings and four new bonds were created in one radical cascade involving intermolecular addition followed by two successive cyclizations and transfer of a xanthate group.

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