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ChemInform Abstract: A Short Synthesis of (.+-.)-Matrine.

✍ Scribed by L. BOITEAU; J. BOIVIN; A. LIARD; B. QUICLET-SIRE; S. Z. ZARD

Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
29
Category
Article
ISSN
0931-7597

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A Short Synthesis of (Β±)-Matrine
A Short Synthesis of (Β±)-Matrine
✍ Laurent Boiteau; Jean Boivin; Annie Liard; BΓ©atrice Quiclet-Sire; Samir Z. Zard πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 104 KB πŸ‘ 1 views

Three different radical reactions were used in a short total synthesis of (Β±)-matrine (1). Two of the four six-membered rings and four new bonds were created in one radical cascade involving intermolecular addition followed by two successive cyclizations and transfer of a xanthate group.