The reaction of CH3 with OH has been studied near 1200 K and 1 atmosphere pressure in shock tube experiments in which UV absorption was used to monitor [OH]. A rate coefficient of (1.1 ? 0.3) x 1013 cm3/mol-s was measured for removal of OH by CH3. This measured value is compared with previous experi
A shock tube study of the reaction of the hydroxyl radical with propane
โ Scribed by J. F. Bott; N. Cohen
- Publisher
- John Wiley and Sons
- Year
- 1984
- Tongue
- English
- Weight
- 537 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0538-8066
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โฆ Synopsis
The rate coefficient for the reaction of the hydroxyl radical, OH, with propane has been measured at 1220 K in shock tube experiments, and a value of (1.58 ? 0.24) x l O I 3 cm3/mol s was obtained. This measured value is compared with previous experimental results and a transition-state theory calculation.
๐ SIMILAR VOLUMES
Reactions of the hydroxyl radical, OH, with several reactants have been studied near 1200 K in shock tube experiments in which UV absorption was used to monitor the OH concentration. The values of the rate coefficients were found to be 2.7 x lo", 2.6 X lo", 2.8 x and 1.26 x 1013 cm3/mol-s for the re
Absolute rate coefficients for the reactions of the hydroxyl radical with ethane (kl, 297-800 K) and propane (kz, 297-690 K) were measured using the flash photolysis-resonance fluorescence technique. The rate coefficient data were fit by the following temperature-dependent expressions, in units of c
The reaction of H atoms with SiCl 4 was studied behind reflected shock waves at temperatures between 1530 K and 1730 K and pressures around 1.5 bar by applying atomic resonance absorption spectroscopy (ARAS) for time resolved measurements of H atoms at the L โฃ -line. The thermal decomposition of a f