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A shock tube study of the reaction of the hydroxyl radical with H2, CH4, c-C5H10, and i-C4H10

✍ Scribed by J. F. Bott; N. Cohen

Publisher: John Wiley and Sons
Year: 1989
Tongue: English
Weight: 725 KB
Volume: 21
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550210702

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✦ Synopsis

Reactions of the hydroxyl radical, OH, with several reactants have been studied near 1200 K in shock tube experiments in which UV absorption was used to monitor the OH concentration. The values of the rate coefficients were found to be 2.7 x lo", 2.6 X lo", 2.8 x and 1.26 x 1013 cm3/mol-s for the reactions of OH with hydrogen, methane, cyclopentane, and isobutane, respectively. These measured values are compared with previous experimental results and transition-state theory calculations.

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