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A scaling procedure in a many-particle derivation of the non-Markovian binary kinetic equations of the reaction A+B→B in liquid solutions

✍ Scribed by A.A. Kipriyanov; I.V. Gopich; A.B. Doktorov

Book ID
108430802
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
107 KB
Volume
244
Category
Article
ISSN
0301-0104

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A many-particle derivation of non-Markov
A many-particle derivation of non-Markovian kinetic equations of reversible reaction A+B⇌C in solutions based on the effective pairs approach
✍ A.A. Kipriyanov; A.B. Doktorov 📂 Article 📅 2003 🏛 Elsevier Science 🌐 English ⚖ 350 KB

The non-Markovian kinetic equations for local concentrations have been derived in the e ective pairs approximation on the basis of the hierarchy for correlation patterns of the reversible reaction A + B C. The equations are shown to agree with the kinetic and thermodynamic detailed balancing princip