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A many-particle derivation of the Integral Encounter Theory non-Markovian kinetic equations of the reversible reaction A+B⇄C in solutions

✍ Scribed by A.B. Doktorov; A.A. Kipriyanov

Book ID
108450259
Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
196 KB
Volume
319
Category
Article
ISSN
0378-4371

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A many-particle derivation of non-Markov
A many-particle derivation of non-Markovian kinetic equations of reversible reaction A+B⇌C in solutions based on the effective pairs approach
✍ A.A. Kipriyanov; A.B. Doktorov 📂 Article 📅 2003 🏛 Elsevier Science 🌐 English ⚖ 350 KB

The non-Markovian kinetic equations for local concentrations have been derived in the e ective pairs approximation on the basis of the hierarchy for correlation patterns of the reversible reaction A + B C. The equations are shown to agree with the kinetic and thermodynamic detailed balancing princip